The sticky feeling on your skin after swimming is not a sign that there is too much chlorine in your pool. It is a sign that there is not enough of the right kind. Here is the actual chemistry behind what you are experiencing, how to test for it specifically, and exactly what to add and when to make it stop.
|
The Fix Available at PoolPartsToGo: Breakpoint chlorination shock: Premium Swimming Pool Shock, 1 lb x 24 bags ($109.99) Pre-shock brushing: Pool Brushes at PoolPartsToGo Ongoing floor debris removal: Pool Robotic Cleaners at PoolPartsToGo |
What Is Actually Causing the Sticky Feeling
The Real Culprit: Combined Chlorine (Chloramines)
When chlorine is added to pool water, it forms hypochlorous acid (HOCl), the active sanitizing form of chlorine. This is called free chlorine. As free chlorine does its job, it bonds with nitrogen-containing compounds from bather waste: sweat, urine, body oils, sunscreen, and other organic material. When free chlorine bonds with these nitrogen compounds, it forms chloramines, also called combined chlorine.
Chloramines are not sanitizing agents. They are spent chlorine. They no longer kill bacteria or oxidize organic material effectively. But they are still chemically active enough to irritate eyes, mucous membranes, and skin on contact. The sticky, slightly slick feeling on your skin after swimming, the red eyes, and the smell that most people call the 'chlorine smell' are all caused by chloramines, not by free chlorine.
This is the critical misunderstanding that leads pool owners to make the problem worse. Smelling what they identify as chlorine, they assume the pool has too much. They stop adding chlorine. Free chlorine levels drop further, allowing more nitrogen compounds to accumulate and form more chloramines. The problem intensifies. The solution is the opposite: adding enough chlorine to reach breakpoint chlorination, the threshold at which chloramines are oxidized and destroyed.
|
What Is Breakpoint Chlorination? Breakpoint chlorination is the process of raising the free chlorine level high enough to chemically destroy combined chloramines rather than simply masking them. The threshold is typically 10 times the combined chlorine reading. A pool with 0.5 ppm combined chlorine must reach a free chlorine level of approximately 5 ppm to break down those chloramines completely. A properly executed breakpoint chlorination treatment should bring combined chlorine to zero. Shocking at half-dose does not reach breakpoint, leaves chloramines partially intact, and is the most common reason pool owners report that shocking 'did not work.' |
Diagnosing Your Pool Water Problem
Sticky or irritating water is the most common symptom, but it is not the only pool water problem that looks like a chemistry issue. Before adding chemicals, identify exactly which problem you have. Different causes have different fixes, and adding the wrong chemical to the wrong problem can make things significantly worse.
|
Symptom |
Most Likely Cause |
Fix |
|
Sticky or slimy feeling on skin after swimming |
Combined chloramines (chloramine buildup). High combined chlorine, often with low free chlorine. |
Breakpoint chlorination: shock the pool at 10x the combined chlorine reading to destroy chloramines. Test combined chlorine with a test kit that measures both free and total chlorine. |
|
Strong 'chlorine smell' at the pool |
Chloramines, not excess chlorine. The 'chlorine smell' most people recognize is actually the smell of chloramines, not free chlorine. |
Shock the pool. Properly sanitized water with free chlorine present has almost no odor. The pungent smell indicates combined chlorine, not high chlorine. |
|
Red, irritated eyes after swimming |
Chloramines reacting with mucous membranes. Often also pH out of range. |
Shock to eliminate chloramines. Test and adjust pH to 7.4 to 7.6. If pH is in range and eyes still irritate, combined chlorine is the primary cause. |
|
Cloudy or hazy water |
Several possible causes: high combined chlorine, pH above 7.8, inadequate filtration, or algae early stage. |
Test pH, alkalinity, and chlorine (free and combined). Run filter at high speed. Shock at 2x standard dose. Brush walls and floor before shocking. |
|
Green or yellow tint, no visible algae |
Early algae formation, low free chlorine, or spring pollen. |
Brush pool first to disrupt biofilm. Shock at 2x to 3x normal dose. Add algaecide if algae growth is confirmed. Run filter 24 hours. |
|
Clear water but swimmers still feel irritation |
pH outside 7.2 to 7.8 range, or chloramines present despite acceptable free chlorine reading. |
Test pH. Even at correct free chlorine levels, pH above 7.8 causes eye and skin irritation. Test total vs. free chlorine to confirm combined chlorine is zero. |
|
Water turns cloudy immediately after adding chlorine |
pH is too high (above 7.8). Chlorine added to high-pH water forms hypochlorous acid inefficiently and can cloud water. |
Lower pH to 7.2 to 7.4 before adding chlorine. Acid first, then chlorine. Allow 15 to 30 minutes between chemical additions. |
|
The Test You Are Probably Not Running Most pool owners test free chlorine and pH. Most pool problems involve combined chlorine and CYA. Standard test strips do not measure combined chlorine, and many do not accurately measure CYA. If your pool water is causing symptoms despite testing 'normal' on your test strips, invest in a liquid DPD drop-test kit or an OTO test kit that measures both free and total chlorine, or bring a water sample to a pool supply store for a full panel. The diagnosis is only as good as the test that produces it. |
The Complete Water Chemistry Reference
Every parameter in pool water affects every other parameter. pH affects how effective chlorine is. Alkalinity affects how stable pH is. CYA affects how available free chlorine is to actually sanitize. Getting the full picture right is easier than troubleshooting one parameter at a time. Here is the complete target range reference:
|
Parameter |
Ideal Range |
Low Warning |
High Warning |
Effect on Swimmer Comfort |
|
Free Chlorine (FC) |
1.0 to 3.0 ppm |
Below 1.0 ppm |
Above 5.0 ppm |
Low FC: inadequate sanitization, chloramines build. High FC: temporary eye irritation, avoid swimming above 5 ppm. |
|
Combined Chlorine (CC) |
0 ppm (ideal) |
N/A |
Above 0.5 ppm |
Any CC above 0.2 ppm begins to cause the sticky skin and chlorine smell symptoms. Target is zero. |
|
pH |
7.2 to 7.8 |
Below 7.2 |
Above 7.8 |
Human eyes are pH 7.4. Outside 7.2 to 7.8, swimmers experience eye and skin irritation regardless of chlorine level. |
|
Total Alkalinity (TA) |
80 to 120 ppm |
Below 80 ppm |
Above 120 ppm |
Low TA causes pH bounce (unstable). High TA pushes pH up and makes it hard to lower. Both affect chlorine effectiveness. |
|
Cyanuric Acid (CYA) |
30 to 50 ppm |
Below 20 ppm |
Above 70 ppm |
CYA protects chlorine from UV. High CYA chlorine lock: chlorine tests adequate but cannot actually sanitize. Chloramine risk rises. |
|
Calcium Hardness |
200 to 400 ppm |
Below 150 ppm |
Above 500 ppm |
Low: water etches plaster and corrodes equipment. High: scale deposits on walls and equipment. Neither directly causes skin irritation. |
|
Temperature |
78 to 82F (typical) |
Below 68F |
Above 90F |
Warm water accelerates chlorine loss and chloramine formation. Increase shock frequency in summer heat. |
|
The Order of Operations for Chemistry Adjustment When multiple parameters are out of range, sequence matters. Adjusting them in the wrong order means re-adjusting after each correction.
Wait at least 2 to 4 hours between each chemical addition and retest before adding the next. Never add two chemicals simultaneously. |
|
Situation |
Corrective Chemical |
How Much and How to Add |
|
pH above 7.8 |
Muriatic acid (pH down) |
Start with 8 to 10 oz per 10,000 gallons. Add to the deep end with pump running. Wait 2 to 4 hours and retest. Add incrementally, not all at once. |
|
pH below 7.2 |
Sodium carbonate (pH up) |
Add 6 oz per 10,000 gallons to raise pH approximately 0.2 points. Pre-dissolve in bucket of water before adding to pool. Retest after 4 hours. |
|
Alkalinity below 80 ppm |
Sodium bicarbonate (baking soda) |
Add 1.5 lbs per 10,000 gallons to raise TA by approximately 10 ppm. Broadcast across surface with pump running. Wait 4 to 6 hours and retest. |
|
Alkalinity above 120 ppm |
Muriatic acid (in doses) |
Lower TA by adding acid with the pump OFF and aeration running, or by adding incrementally with pump ON. Lower TA before adjusting pH. |
|
CYA above 70 ppm |
Partial drain and refill |
There is no chemical that removes CYA. Drain 25 to 30 percent of pool water and refill with fresh water. Retest and adjust chemistry. Do not add more stabilizer for the remainder of the season. |
|
CYA below 20 ppm |
Cyanuric acid stabilizer |
Add 4 oz per 10,000 gallons to raise CYA by approximately 6 ppm. Do not add above 50 ppm if using Cal Hypo shock regularly. |
|
High combined chlorine |
Cal Hypo shock (breakpoint) |
Add 10x the combined chlorine reading in pounds of Cal Hypo per 10,000 gallons, with a minimum of 1 lb per 10,000 gallons. Shock at dusk. Run pump overnight. Retest in the morning. |
|
CYA Is the Parameter Most Pool Owners Undertest and Overload Cyanuric acid accumulates with every use of stabilized chlorine products (Dichlor, Trichlor tablets). Most pool owners add stabilizer once in spring and never test it again. Over a full season of tablet use, CYA commonly climbs to 80 to 100 ppm or higher. Above 70 to 80 ppm, free chlorine is chemically bound to the CYA molecule and cannot react with contaminants effectively. This condition (chlorine lock) means your pool tests as having adequate free chlorine while bacteria and chloramine precursors accumulate unchecked. The only remedy is a partial drain and refill. Using stabilizer-free Cal Hypo shock for regular treatments prevents this accumulation. |
Choosing the Right Shock Product
Not all shock products achieve breakpoint chlorination with the same efficiency or the same chemical consequences. The type of shock matters as much as the dose.
|
Shock Type |
Active Ingredient |
CYA Impact |
Best Use |
Risk |
|
Cal Hypo (68%) (PPTG Premium Shock) |
Calcium hypochlorite |
None (stabilizer-free) |
Weekly maintenance, opening, closing, algae treatment, chloramine elimination |
Raises calcium hardness slightly. Do not pre-dissolve in bucket. Add directly to pool. |
|
Dichlor |
Sodium dichloro- isocyanurate |
Adds CYA each use |
Occasional use only. Good for dissolving easily. |
Repeated use raises CYA over 70 ppm, causing chlorine lock. Do not use for weekly shock. |
|
Trichlor (tablets) |
Trichloroisocyanuric acid |
Adds CYA each use |
Slow-release sanitizer (tablets). Not a shock product. |
Continuous CYA accumulation. Highly acidic; lowers pH. Never use as shock treatment. |
|
Non-chlorine shock |
Potassium monopersulfate (MPS) |
None |
Oxidizing bather waste without raising chlorine. Can be used before swimming (wait time shorter). |
Does not kill algae or eliminate chloramines effectively. Not a replacement for Cal Hypo shock. |
|
Why 68% Cal Hypo Is the Right Product for Weekly Shocking and Chloramine Treatment The Premium Swimming Pool Shock at PoolPartsToGo is 68% calcium hypochlorite, stabilizer-free, in full 1 lb pre-measured bags. The high concentration means each bag delivers meaningful free chlorine per pound of product. The stabilizer-free formula means you can shock weekly through an entire season without accumulating CYA. The 1 lb per bag format eliminates the most common dosing error: partial bags that leave the product exposed to moisture and lose potency before the next use. Each bag is a complete dose for a 10,000-gallon pool at maintenance levels, with no measuring, no partial scooping, and no guessing. |
The Breakpoint Chlorination Protocol
Here is the complete step-by-step process for treating a pool with chloramine buildup. This protocol applies to any pool with sticky water, chlorine smell, or eye irritation that does not resolve with standard chlorine maintenance.
|
1 |
Test your water: free chlorine AND total chlorine You need a test kit that measures both free chlorine and total chlorine, not just free chlorine. Combined chlorine = total chlorine minus free chlorine. Most test strips measure free chlorine only. If you only have test strips, buy a liquid drop-test kit or bring a sample to a pool supply store for a full panel reading. Note: A pool with free chlorine reading of 2 ppm that also reads 2.5 ppm total chlorine has 0.5 ppm combined chlorine. That 0.5 ppm CC is the source of the sticky feeling and chlorine smell. |
|
2 |
Test and correct pH before shocking Cal Hypo shock is most effective between pH 7.2 and 7.6. If pH is above 7.8, add muriatic acid first and allow 2 to 4 hours before shocking. Shocking into high-pH water wastes product and reduces the chlorine's ability to reach breakpoint. Adjust pH first, shock second. |
|
3 |
Calculate your shock dose To reach breakpoint chlorination and destroy combined chloramines, you must raise the free chlorine level to at least 10 times the combined chlorine reading. Formula: required dose (ppm) = combined chlorine x 10. One pound of 68% Cal Hypo shock raises free chlorine by approximately 6 to 7 ppm in 10,000 gallons. For a 10,000-gallon pool with 0.5 ppm CC, you need to raise FC by at least 5 ppm, which is approximately one 1 lb bag of the Premium Pool Shock. Note: When in doubt, use a full 1 lb bag per 10,000 gallons. Under-dosing is the most common reason shocking does not resolve chloramine problems. |
|
4 |
Brush the pool walls and floor first Before adding shock, brush the entire pool interior: walls from top to bottom, steps, ledges, and floor. Brushing disrupts the surface biofilm that harbors bacteria and chloramine precursors. Shock that reaches clean surfaces is significantly more effective than shock that must penetrate biofilm to work. |
|
5 |
Add shock at dusk with the pump running Broadcast the shock evenly across the pool surface while walking around the perimeter. Concentrate slightly more in the deep end where circulation tends to be weakest. Never add shock to a bucket of water first for Cal Hypo. Add directly to the pool with the pump running at high speed. Evening or dusk application prevents UV from degrading the un-stabilized chlorine before it can reach breakpoint. Note: Do not shock before a swim session expecting to swim the same day. Shocking is an overnight process. Test free chlorine the following morning before swimming. |
|
6 |
Run the pump at high speed overnight Set your pump to its highest speed and run it through the night. Full circulation ensures the shock reaches every part of the pool volume. Any dead zones (behind ladders, corners, steps) that miss circulation will retain chloramines even after a successful shock treatment of the main pool body. |
|
7 |
Retest in the morning: free chlorine must be below 3 ppm before swimming Test free chlorine and combined chlorine. Free chlorine should have dropped from its elevated shock level back toward 1 to 3 ppm. Combined chlorine should be at or near zero. If CC is still above 0.2 ppm after one treatment, repeat the shock dose the following evening. Some heavily contaminated pools require two to three consecutive shock treatments to eliminate chloramine buildup completely. |
|
What to Expect After Shocking: Day-by-Day Day 1 (day of shocking): Pool may appear slightly milky or hazy as chloramines break down. This is normal. Do not swim. Day 2 (morning after): Water should be clearer. Test free chlorine (should be dropping back toward 1 to 3 ppm) and combined chlorine (should be near zero). If CC is still above 0.2 ppm, shock again. Day 3 (if second shock was needed): Retest. Most pools clear to zero combined chlorine within two consecutive shock treatments. If CC persists, consider whether CYA is above 70 ppm (which prevents chlorine from working) or whether there is a persistent organic source entering the pool (runoff, heavy bather load). When to swim: When free chlorine drops below 3 ppm (ideally 1 to 2 ppm) and combined chlorine is zero or less than 0.2 ppm. Do not rely on time alone. Test before swimming. |
Keeping Chloramines from Coming Back
Once you have eliminated chloramines with a successful breakpoint chlorination treatment, the question is how to prevent them from rebuilding. The answer is consistent maintenance chemistry rather than reactive treatment.
|
The Weekly Habits That Prevent Chloramine Buildup
|
The Product That Fixes It
|
Blue Torrent Power Shock (68% Cal Hypo, Stabilizer-Free) $109.99 (was $189.99) Premium Swimming Pool Shock - 1 lb Packs (24 Count) Full-strength 68% calcium hypochlorite in pre-measured 1 lb bags, 24 bags per box. Stabilizer-free formula does not add cyanuric acid, preventing the chlorine lock that follows repeated use of stabilized shock products. Each 1 lb bag is the correct dose for a standard 10,000-gallon pool maintenance shock. For breakpoint chlorination (chloramine elimination), use 1 to 3 bags depending on combined chlorine level measured. Broadcast directly into the pool with the pump running at dusk. Wait until free chlorine drops below 3 ppm before swimming. Note: Pool chemicals are non-refundable. |
Fix It Tonight. Keep It Fixed All Season.
The sticky feeling, the smell, and the red eyes are all symptoms of the same root cause: chloramines. Breakpoint chlorination with a full-strength Cal Hypo shock resolves it in one overnight treatment in most cases. Combine that with a weekly shock schedule, regular brushing, and accurate chemistry testing, and your pool water should stay comfortable and clear for the entire season.
|
Products at PoolPartsToGo: Premium Swimming Pool Shock, 1 lb x 24 Bags ($109.99) |
Frequently Asked Questions
Why does my pool smell like chlorine even though my chlorine level tests fine?
The smell you are identifying as chlorine is almost certainly chloramines (combined chlorine). Free chlorine in a properly balanced pool is largely odorless. The pungent, eye-watering smell that most people associate with chlorinated pools is the smell of chloramines, which form when free chlorine bonds with nitrogen compounds from bather waste. Test your pool using a kit that measures both free chlorine and total chlorine. If total chlorine is higher than free chlorine, combined chlorine is present and a shock treatment is needed.
How do I test for combined chlorine?
You need a test kit that measures both free chlorine (FC) and total chlorine (TC). Combined chlorine = TC minus FC. Standard OTO test kits (the yellow indicator) measure total chlorine. DPD test kits measure free chlorine. You need either a two-reagent DPD kit that does both, or a digital photometer test kit for accuracy. Most pool supply stores can do a full panel for free if you bring a water sample in a clean container. Once you know your combined chlorine number, you can calculate the correct shock dose.
How much shock do I need to eliminate chloramines?
The formula is 10 times the combined chlorine reading as the required free chlorine target, which then determines how many pounds of shock to add. One pound of 68% Cal Hypo raises free chlorine by approximately 6 to 7 ppm in 10,000 gallons. For a pool showing 0.5 ppm combined chlorine, you need to raise free chlorine by at least 5 ppm (10 x 0.5 ppm), which is approximately one 1 lb bag per 10,000 gallons. For heavier chloramine loads (CC above 1 ppm), use 2 to 3 bags. When in doubt, use the higher dose. Under-dosing wastes the product and leaves chloramines in the water.
Can too much CYA cause sticky pool water?
Yes, indirectly. When CYA rises above 70 to 80 ppm, it chemically binds with free chlorine and reduces the amount that is available to react with contaminants. This means organic nitrogen compounds accumulate and form chloramines even when your free chlorine reading looks adequate. If you are shocking regularly but combined chlorine keeps rebuilding, test your CYA level. If it is above 70 ppm, a partial water change is the only remedy. Cal Hypo shock (stabilizer-free) prevents this from happening by not adding CYA with each treatment.
Is it safe to swim right after shocking?
No. After a shock treatment, free chlorine levels are elevated well above safe swimming levels (often 5 to 10+ ppm depending on dose). Wait until free chlorine drops below 3 ppm before swimming. For a standard evening shock with the pump running overnight, the pool is typically ready for swimming the following afternoon. Test before allowing anyone in the water. Do not rely on time alone: pool volume, temperature, and sun exposure all affect how quickly free chlorine dissipates after shocking.
Do I need to shock my pool if I have a salt water system?
Yes. Salt water pools generate free chlorine through the salt cell, but they are just as susceptible to chloramine accumulation as traditionally chlorinated pools. The salt cell does not inherently destroy combined chlorine. If your salt pool has the sticky-skin or chlorine-smell symptom, test for combined chlorine and shock with Cal Hypo just as you would with a traditionally chlorinated pool. Cal Hypo is compatible with salt water systems.

